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二茂铁衍生物的合成和表征

Synthesis and Characterization of Ferrocene Derivatives

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【作者】 陈勇杨光张新兵刘惠英

【Author】 CHENG Yong 1,YANG Guang 1,ZHANG Xin-bing 1,LIU Hui-ying 2 (1.Department of Chemical Engineering,Jiangsu Institute of Petrochemical Technology,Changzhou 213016,China;2.Department of Chemistry, Wuhan University, Wuhan 430072,China)

【机构】 江苏石油化工学院化学工程系武汉大学化学系 江苏常州213016江苏常州213016湖北武汉430072

【摘要】 由二茂铁和芳胺作为原料通过芳基化作用合成了 3个新二茂铁衍生物。通过元素分析、IR、1 HNMR和MS确证了化合物结构。这些化合物的其它性质和用途还有待研究

【Abstract】 In the investigation,three new ferrocene derivatives were synthesized by arylation,using ferrocene and arylamines as the starting materials.The structures of these new derivatives were confirmed by elementary analysis,IR, 1HNMR and MS.The other properties and uses of these compounds are yet to be studied.The yields of three products were 17 3%,10 2% and 20 3%,respectively.The tests found that the key step is the preparation of diazotization of arylamine.The result showed that the appropriate reaction conditions should be:sulfuric acid as reaction medium;at room temperature.

【关键词】 二茂铁衍生物合成表征
【Key words】 ferrocene derivativesynthesischaracterization
【基金】 江苏石油化工学院科研基金资助
  • 【文献出处】 江苏石油化工学院学报 ,Journal of Jiangsu Institute of Petrochemical Technology , 编辑部邮箱 ,2002年02期
  • 【分类号】O627.8
  • 【被引频次】2
  • 【下载频次】377
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