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载体预处理对炭化树脂负载磷钨酸催化剂烷基化活性的影响

Effect of Pretreatment on the Adsorption of PW12on the Carbonized Resin and its Catalytic Activity

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【作者】 张龙高伟民王亚君

【Author】 ZHANG Long1,GAO Weimin1,WANG Yajun2(1.School of Chemical Engineering,Changchun University of Technol, Changchun 130012, China;2Qianguo Petro Refinery, Songyuan 138000, China)

【机构】 长春工业大学化学工程学院前郭炼油厂 吉林长春130012吉林长春130012吉林松原138000

【摘要】 烷基化反应中一直沿用的催化剂H2 SO4,HF对环境污染较大 ,腐蚀设备与产物分离困难。文中详细讨论了影响固体酸催化剂PW12 在炭化树脂吸附过程中受预处理的影响。通过实验确定此催化剂制备过程中的适宜预处理条件 ,如预处理溶剂 ,预处理溶剂的浓度。并结合理论进行了分析。

【Abstract】 Existing industrial alkylation processes employ corrosive and environmental hazardous HF and H2SO4 as catalysts The catalysts have many disadvantages such as pollution , corrosion and difficulty of separating the product and the catalyst For these safety and environmental reasons their substitution with a noncorrosive solid catalyst is desirable This research focuses on the adsorption of the PW12 on carbonized resin which has high activity and is environmental friendlyThe relationship between the acid pretreatment and the activity of catalyst has been studied experimentally and the best pretreatment condition was obtained A theoretical analysis is made

【基金】 吉林省科技厅科学技术发展基金资助项目(吉科合字第970523 1号)
  • 【文献出处】 长春工业大学学报(自然科学版) , 编辑部邮箱 ,2002年S1期
  • 【分类号】O643.3
  • 【下载频次】84
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