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化学沉积Ni-Co-P合金电极在碱性介质中的析氢电催化性能
The catalytic property of electroless Ni-Co-P alloy electode in alkaline media
【摘要】 用化学镀方法制备了Ni-P,Ni-Co-P合金电极,用电子能谱仪、扫描电镜(SEM)、X射线衍射测量了化学镀Ni-P,Ni-Co-P合金的组成、形貌结构、晶形.用电化学的方法研究了Ni-P,Ni-Co-P合金作阴极在1mol·L-1NaOH溶液中的析氢催化活性及稳定性,结果表明Ni-P,Ni-Co-P合金电极具有良好的析氢电催化性能和电化学稳定性.
【Abstract】 NiP,NiCoP alloy electodes were prepared by electroless method.Their components?structures and figures were measured with PV9100,X ray and SEM . As cathodes in 1 mol·L-1 NaOH,their electrocatalytic properties of hydrogen evolution and stability were studied by electrochemical methods. The results showed that the alloy electrodes had good electrocatalytic properties of hydrogen evolution and good electrochemical stability.
【关键词】 化学沉积;
组成;
形貌结构;
析氢反应;
电催化;
稳定性;
【Key words】 electroless; component; structure; hydrogen evolution reaction; electocatalytic properties; stability;
【Key words】 electroless; component; structure; hydrogen evolution reaction; electocatalytic properties; stability;
【基金】 国家"火炬"计划资助项目(9324215007).
- 【文献出处】 华中师范大学学报(自然科学版) ,Journal of Central China Normal University(Natural Sciences) , 编辑部邮箱 ,2002年04期
- 【分类号】TQ153
- 【被引频次】17
- 【下载频次】224