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含铁氨羧螯合树脂配体交换除氟研究

Study on Removing Fluorine from Water through the Ligand Excha nge of a Chelating Type Amine_Carboxyl Group Resins Containing Iron

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【作者】 刘建李梦耀赵金辉王艳霞

【Author】 LIU Jian 1, LI Meng_Yao 1, ZHAO Jin_hui 2, WANG Yan_xia 2 1 Department of Applied Chemistry, 2 Department of Water Resourrc es and Surrounding Engineering, Changan University, Xian 710054, Shaanxi, C hina)

【机构】 长安大学应用化学系长安大学水资源与环境工程系长安大学水资源与环境工程系 陕西西安710054陕西西安710054陕西西安710054

【摘要】 报道了以D40 1型氨羧螯合树脂螯合固载铁 (Fe3 + ) ,利用水溶液中F-可与Fe3 + 形成稳定配合物性质 ,实现了配体交换固液分离去除高氟水中的氟 .实验研究了该种分离材料在含氟水的除氟性能和条件 .结果表明 ,含氟 1 0~ 2 0mg L左右的水溶液中 ,除氟率可达 99%以上 ,可使氟含量降至 0 0 5mg L以下 ,经测定 ,树脂对氟的吸附量可达 2 7mgF- g_R ,水中常见共存离子对氟离子的吸附无影响 ,表现出树脂除氟过程的高度选择性

【Abstract】 In this thesis, a new method that removing fluoine from water including fluoride using type of D401 chelating resins was reported. In t his method, the first the resin adsorbs and immobilizes iron(Fe 3+ ), then t he properties of coordination of fluorine ions (F -) and iron cation (Fe 3+ ) in water solution was utilized, the fluoring can be separated between solid_ liquid phases. The test result shows that the 99% of fluor was removed from wat er including fluorine about 10~20mg/L, and fluorine contents in water can fall to below 0 05mg/L, the static saturation adsorbing capacity is 2 7mg F -/g_ R. Other hands, test result shows as well, common_ions in water do not make affe ct to adsorbing fluor ions by the resin. A high selectin in proccss of removing fluorins has been demonstrated.

【关键词】 D401螯合树脂吸附除氟
【Key words】 fluoineD401 chelating resinadsorptionremoving flu oine
  • 【文献出处】 汉中师范学院学报(自然科学) ,Journal of Hanzhong Teachers College , 编辑部邮箱 ,2002年03期
  • 【分类号】O647.3
  • 【被引频次】12
  • 【下载频次】161
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