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包埋Ru(bpy)3Cl2的非线性光催化薄膜的制备和表征
Preparation and Characterization of Nonlinear and Light-excitable Catalysis Membrane Containing Ru(bpy)3Cl2
【摘要】 采用溶胶 -凝胶法在正硅酸乙酯水解的溶液中加入Ru(bpy)3Cl2 ,在非常温和的条件下制备出具有多孔结构的薄膜.并利用FTIR,AFM,N2 吸附等测试手段对其进行了表征,验证了Ru(bpy)3Cl2 在Belousov Zhabotinsky反应中的光催化活性.结果表明Ru(bpy)3Cl2 被包埋在多孔结构中,使薄膜在BZ反应中具有了光催化性能
【Abstract】 In this contribution, Ru(bpy)3Cl2 was successfully immobilized into the sol-gel matrix under very mild conditions. FTIR, AFM and BET of N2 adsorption were used to characterize the porous membrane, which show that Ru(bpy)3Cl2 is embedded in the pore. The as-prepared membrane can catalyze the BZ (Belousov-Zhabotinsky) reaction by illumination, showing that it can be used as light-catalyst for non-symmetrical phase BZ reaction for image processing.
【关键词】 Ru(bpy)3Cl2;
溶胶-凝胶法;
光催化;
BZ反应;
【Key words】 Ru(bpy)3Cl2; sol-gel method; light-catalysis; BZ reaction;
【Key words】 Ru(bpy)3Cl2; sol-gel method; light-catalysis; BZ reaction;
【基金】 国家自然科学基金(No.698310 10)重点资助项目
- 【文献出处】 化学学报 ,Acta Chimica Sinica , 编辑部邮箱 ,2002年12期
- 【分类号】O643.3
- 【被引频次】2
- 【下载频次】175