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LiCl/MnO2-H3BO3体系甲烷氧化偶联催化剂的研究
Oxidative Coupling of Methane on LiCl/MnO2-H3BO3 Catalyst
【摘要】 由于石油资源的日见枯竭 ,天然气在化工原料中的地位日益突出。对天然气的主要成分甲烷、氧化偶联 (OCM)制备乙烯的催化剂—— Li Cl/Mn O2 - H3 BO3 进行了系统研究并探讨了其组分及外界反应条件对该催化剂性能的影响 ,发现了可能的活性组分 :立方晶型的 Li4 B7O12 Cl。
【Abstract】 Because of the rising price and the exhaustion of petroleum, the role of nature gas as raw material has become more and more important in chemical industry. The catalysts——LiCl/MnO2-H3BO3 for oxidative coupling of methane (OCM) have been investigated. The results show the catalysts possess high activity and selectivity. Furthermore, the influence of the components of the catalysts and the reactive conditions were explored and find the possible active component——cubic Li4B7O 12Cl.
【基金】 上海市科技发展基金资助项目 ( 0 2 30 12 0 0 7)
- 【文献出处】 化学世界 ,Huaxue Shijie (Chemical World) , 编辑部邮箱 ,2002年12期
- 【分类号】O643.36
- 【被引频次】1
- 【下载频次】75