【摘要】 通过三异丁基铝和四氯化碳反应制得氯化二异丁基铝。在芳烃溶液中,氯化二异丁基铝进一步和叠氮化钠反应合成了新化合物叠氮二异丁基铝(DBAA);以四氢呋喃为溶剂,合成DBAA时则得到了新化合物叠氮二异丁基铝和四氢呋喃的配合物(DBAA·THF)。用红外光谱、核磁共振谱等技术对这两个化合物的结构进行了表征;研究讨论了这些化合物的性质。更多还原

【Abstract】 <Abstrcat> Diisobutyl aluminum chloride is synthesized by the reaction of triisobutyl aluminum and carbon tetrachloride. Diisobutyl aluminum azide (DBAA) is synthesized by the reaction of the sodium azide and diisobutyl aluminum chloride in arenes, and its complex(DBAA·THF) is also synthesized through the reaction of the sodium azide and diisobutyl aluminum chloride in tetrahydrofuran. DBAA and DBAA·THF are characterized by IR and HNMR spectrum. The properties of DBAA and DBAA·THF are also studied. 更多还原