【摘要】 合成了5-[对 -N -谷氨酸丁氧基)苯基] -10,15,20 -三(对氯苯基)卟啉(H2L)及其配合物MLCl(M=Co,Fe,Mn) ,并对它们进行了元素分析、UV -cis、荧光光谱、IR和1HNMR等结构表征。催化实验发现 ,除配体外 ,3种配合物在分子氧氧化苯甲醛的反应中具有催化作用更多还原

【Abstract】 Meso-5-[p-N-glutamic acid butoxyl)phenyl]-10,15,20-tri(p-chlorophenyl)porphyrin(H2L)and its complexes MLCl(M=Co,Fe,Mn)were synthesized and were characterized by 1HNMR,IR,UV-vis and fluorescence spcetra.The oxidation of aromatie aldehyes with O2 has been investigated in the presence of complexes.It was observed the complexes MLCl can all catalyze the oxidation aromatic aldehydes,while H2L is inactive,CoL is the better catalyst compared with other tailed amino acid porphyrins in the same condition.更多还原