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一步脱氟制备饲料级磷酸氢钙及硫酸铵新工艺
Process for Producing of Feed Calcium Hydrophosphate by One Step De-fluorination and By-producing of Ammonia Sulfate
【摘要】 介绍用硫酸萃取磷矿粉生产磷酸 ,然后经一步脱氟、氢氧化钙中和、过滤、干燥生产饲料级磷酸氢钙 ;再利用反应生成的磷石膏与碳铵反应制备碳酸钙和硫酸铵的新工艺。该工艺解决了磷石膏中的钙无法充分利用的问题 ,充分合理地利用了资源 ;另外采用一步脱氟生产肥料级磷酸氢钙 ,大大提高了磷矿石中磷转化到饲料级磷的比例 ,显著地降低了生产成本 ,简化了工艺
【Abstract】 This paper deals with a novel process for producing feed calcium hydro-phosphate.The process comprises using sulfuric acid to extract ground phosphate rock to produce phosphoric acid, de\|fluorinating by one step, neutralizing hydrated lime, filtrating and drying to produce feed calcium hydrophosphate and making use of the phosphogypsum reacting with ammonia hydrogen carbonate to produce by-products. The process solves the failure to making full use of calcium in phosphogypsum, and utilizes the resources reasonably. Moreover, one step de-fluorination improves the conversion from the phosphorus in ground phosphate rock to the phosphorus in feed calcium hydrophosphate, decreases the product cost remarkably and reduces the process steps.
【Key words】 sulfuric acid; ground phosphate rock; ammonia sulfate; feed calcium hydrophosphate; novel process;
- 【文献出处】 化工进展 ,Chemical Industry and Engineering Progress , 编辑部邮箱 ,2002年07期
- 【分类号】TQ132.32
- 【被引频次】1
- 【下载频次】144