【摘要】 以 6,7-二甲硫基四硫富瓦烯 -2 ,3 -二硫盐为配体合成了 3种未见文献报道的双 (6,7-二甲硫基四硫富瓦烯 -2 ,3 -二硫 )金属配合物 ,为“桥式”四硫富瓦烯衍生物的合成创造出一种新方法 ,并对只得到中性产物提出了合理的解释。研究了其 IR及室温电导率更多还原

【Abstract】 Treatement of ligand 6,7 bismethylthio tetrathiafulvalene 2,3 dithiolate salt with metal(Ⅱ) cations yielded new three bis(6,7 bismethylthio tetrathiafulvalene 2,3 dithio)matal complexes. This is a new method of synthesizing bridged tetrathiafulvalene derivatives. The room temperature conductivity and IR of the complexes were reported.更多还原