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25℃K2SO4-(NH4)2SO4-H2O体系溶解度计算
Solubility Calculation of K2SO4-(NH4)2SO4-H2O System at 25℃
【摘要】 依据Pitzer电解质溶液理论对含有固溶体结晶区的K2SO4-(NH4)2SO4-H2O水盐体系溶解度进行了计算,计算值与实验确定值相吻合,并针对该体系相图固溶体结晶区不易实验确定的问题,提出了计算确定的方法.
【Abstract】 On the basis of Pitzer electrolyte solution theory, solubility of K2SO4-(NH4)2SO4-H2O aqueous salt system which contains a solid solution region is calculated, the calculated value agrees with experiment results. In accordance with the problem that solid solution region is not easy determined in the phase diagram of the above system, a method to determine a solid solution region is put forward.
【关键词】 硫酸钾;
硫酸铵;
溶解度计算;
相平衡;
固溶体;
【Key words】 potassium sulfate; ammonium sulfate; solubility calculation; phase equilibrium; solid solution;
【Key words】 potassium sulfate; ammonium sulfate; solubility calculation; phase equilibrium; solid solution;
【基金】 河北省自然科学基金资助项目(200004);省教委博士基金资助项目
- 【文献出处】 河北工业大学学报 ,Journal of Hebei University of Technology , 编辑部邮箱 ,2002年05期
- 【分类号】O642.42
- 【被引频次】10
- 【下载频次】204