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ENR-25改性CaCO3填充LDPE的复合材料的研究

Research on the LDPE Composite Filled with CaCO3 Modified by ENR 25

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【作者】 李志君汪志芬张安花邓国强

【Author】 LI Zhi jun, WANG Zhi feng, ZHANG An hua, DENG Guo qiang (College of Technology, South China University of Tropical Agriculture, Hainan 571737, China)

【机构】 华南热带农业大学工学院高分子材料与工程系华南热带农业大学工学院高分子材料与工程系 海南海口571737海南海口571737海南海口571737

【摘要】 用环氧化程度为 2 5 %的环氧化天然橡胶 (ENR - 2 5 )改性轻质CaCO3 。研究了改性方法、改性剂用量、CaCO3 填充量对低密度聚乙烯 (LDPE)材料结构与性能的影响。结果表明 ,7.5 %的ENR - 2 5湿法改性有效地改善了CaCO3 在LDPE中的分散性及相容性 ,增强了界面作用强度 ,使材料在拉伸强度保持较高的情况下 ,拉伸弹性模量、撕裂强度和断裂伸长率得到有效的提高

【Abstract】 Light CaCO 3 was modified by ENR 25. The influence of modification method, ENR 25 content and CaCO 3 filling content on the micro morphologies and the mechanical properties of composites were investigated. It is found that the modification is effective with the ENR 25 latex for the addition of 7.5%. The decentralization of CaCO 3 in LDPE matrix, the compatibility of LDPE/ CaCO 3 and the interfacial interaction between CaCO 3 and LDPE matrix are improved effectively. The tensile strength of the LDPE composite filled with modified CaCO 3 is also kept when the tensile modulus and tear strength and elongation at break is enhanced.

【关键词】 环氧化天然橡胶低密度聚乙烯改性碳酸钙复合材料
【Key words】 ENRLDPEmodified CaCO 3composite
  • 【文献出处】 功能高分子学报 ,Journal of Functional Polymers , 编辑部邮箱 ,2002年01期
  • 【分类号】TQ325.14
  • 【被引频次】8
  • 【下载频次】131
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