节点文献
具有四帽假Keggin结构“簇阴离子对”的多金属氧簇[Co(2,2-bipy)3]4[Mo5ⅤMo5ⅥV6ⅣO40(PO4)]2·4H2O的水热合成与晶体结构
Hydrothermal Synthesis and Crystal Structure of [Co(2,2-bipy)3]4[Mo5ⅤMo5ⅥV6ⅣO40(PO4)]2·4H2O Containing Double Tetracapped Pseudo-Keggin Cluster Anions
【Abstract】 The title compound[Co(2,2-bipy) 3] 4[Mo 10V 6O 40(PO 4)] 2·4H 2O was synthesized by hydrothermal method and its structure was determined with single crystal X-ray analysis. The cluster anion is double tetracapped Pseudo-Keggin cluster anions. The crystal is triclinic, space group P-1 with a=\{1\^316 5(3)\} nm, b=1\^438 2(3) nm, c=2\^764 4(6) nm, α=79\^51°, β=89\^95°, γ=68\^89°, V=\{4\^789 3(17)\} nm 3, Z=1, D c=2\^176 g/cm 3, R=0\^075 5, wR=0\^205 3, S=0\^995.
【基金】 国家自然科学基金(批准号 :2 0 1710 45 );国家财政部基金;中国科学院“引进国外杰出人才”专项基金;高等学校博士学科点专项科研基金资助
- 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,2002年10期
- 【分类号】O641
- 【下载频次】98