【摘要】 利用时间分辨激光光解技术对稀有三环核苷的前体化合物N - 4-desmethylwyosine(dYt)研究发现 ,该化合物能被 2 4 8nm激光单光子电离 ,但未观察到明显的激发三线态。用氧化性自由基SO4 · - 引发其阳离子自由基 ,揭示了其光电离机理。以KI溶液为参照 ,测得该化合物中性条件下的光电离量子产额 (Φe- )为 0 .0 4。更多还原

【Abstract】 The absorption spectra of N-4-desmethylwyosine (dYt), a derivative of the tricyclic modified nucleoside wyosine, in aqueous solutions were studied by time-resolved laser photolysis. The oxidizing radical SO 4 ·- was used to produce dYt radical cation. The mechanism of dYt monophotonic ionization was suggested. Distinct triplet was not observed in this work. The quantum yield of formation of hydrated electrons ( Φ e -) was determined to be 0.04 at room temperature in neutral aqueous solution by using KI solution as a reference.更多还原