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环己烷激发态超常能量传递速率常数的研究II—TOPO高效的能量接受剂
A STUDY ON THE ABNORMAL RATE CONSTANT OF EXCITED ENERGY TRANSFER FROM CYCLOHEXANEEXCITED STATE TO TRIOCTYLE PHOSPHINE OXIDE II-TOPO A HIGH EFFICIENT ENERGY ACCEPTOR
【摘要】 研究了三辛基氧化膦 (TOPO)—环己烷体系的主要γ辐解产物氢气、二环己烷和环己烯的产额 ,由此计算了环己烷激发态能量传递的速率常数k约为 1.4× 10 13L·mol·s- 1,证明存在超常的激发态能量传递过程
【Abstract】 An abnormal rate constant about 1.4×10 13 L -1 ·mol·s -1 of excited energy transfer has been found in the γ radiolysis of C 6H 12 -TOPO system by analyzing the main radiolysis products hydrogen, cyclohexene and bicyclohexyl
【关键词】 三辛基氧膦(TOPO);
环己烷;
γ辐解;
能量传递;
超常速率;
【Key words】 Cyclohexane (C 6H 12 ); Trioctyl phosphine oxide (TOPO); γ radiolysis; Energy transfer; Abnormal rate constant;
【Key words】 Cyclohexane (C 6H 12 ); Trioctyl phosphine oxide (TOPO); γ radiolysis; Energy transfer; Abnormal rate constant;
【基金】 研究奖励基金资助
- 【文献出处】 辐射研究与辐射工艺学报 ,Journal of Radiation Research and Radiation Processing , 编辑部邮箱 ,2002年03期
- 【分类号】O621.1
- 【被引频次】1
- 【下载频次】21