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Modulation of Electrochemical Oscillations by Specific Adsorption of Cl- during the Electrooxidation of Methanol on Pt Electrode

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【Author】 Ze Lin LI *, Ji Hua HUANG, Xiao Ming XIAO, Yue ZENG, Xia CHU Department of Chemistry, Hunan Normal University, Changsha 410081

【Abstract】 Potential oscillation during the electrocatalytic oxidation of methanol can be modulated by the specific adsorption of Cl- on the platinum electrode, which suppresses the electrocatalytic oxidation of methanol, and makes the cross cycle in the cyclic voltammogram become smaller and finally disappear with the increase of Cl- concentration. The method is also applicable to the electrocatalytic oxidation of other small organic molecules.

【基金】 Financial support by the National Natural Science Foundation of China (20073012) is gratefully acknowledged.
  • 【文献出处】 Chinese Chemical Letters ,中国化学快报(英文版) , 编辑部邮箱 ,2002年03期
  • 【分类号】O646.5
  • 【被引频次】1
  • 【下载频次】12
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