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聚丙烯酰胺存在下微波高压合成银纳米粒子及其光谱特性
Preparation of Silver Nanoparticles in the Presence of Polyacrylamide by Microwave High-pressure Synthesis Method and Its Spectral Properties
【摘要】 以聚丙烯酰胺为还原剂和稳定剂 ,采用微波高压液相合成法制备了黄色银纳米粒子。用吸收光谱和共振散射光谱研究了其制备条件的影响。在 4 2 1.6nm处产生最大吸收峰 ,在 4 70nm处产生一个最强共振散射峰。实验表明 :该法制备的银纳米粒子粒径均匀 ,平均粒径为 6 6nm ,其稳定性和分散性较好 ,合成方法简便、快捷。
【Abstract】 The silver nanoparticles in yellow color were prepared by microwave high pressure synthetical method, using polyacrylamide as reducing agent and stabilizer. The maximun absorption peak of silver colloidal is at 421.6 nm, and its strongest resonance scattering peak is at 470 nm. The influence of main conditions on the microwave reaction was studied with absorption spectrometry and resonance scattering spectroscopy. The experimental the result showed that the silver nanoparticles had well distributity and good stability. The average diameter of silver nanoparticles is 66 nm. The procedure was rapid and convenient.
【Key words】 Polyacrylamide; silver nanoparticle; microwave high pressure synthesis; resonance scattering spectroscopy;
- 【文献出处】 分析化学 ,Chinese Journal of Analytieal Chemistry , 编辑部邮箱 ,2002年10期
- 【分类号】O657.3
- 【被引频次】22
- 【下载频次】217