【摘要】 从理论上探讨了在胶束电动力学毛细管色谱中采用迁移时间来定性的不足 ,提出将相对有效淌度用于该体系下尿中核苷组分的定性。结果表明 :使用相对有效淌度作定性指标 ,其平均相对标准偏差为1 5 4 % ,明显优于用迁移时间进行定性所得的平均相对标准偏差 7.9%。提出用识别系数评价定性的可靠性。当使用相对有效淌度作定性指标时 ,75 %以上的分析物都达到了可靠识别。识别可靠性与采用迁移时间相比最高可提高 16倍更多还原

【Abstract】 Relative mobility was taken as a tool to investigate the peak identification in micellar electrokinetic capillary chromatography (MEKC). The precision (average RSD) of relative mobility was 1.5%, which was much better than the peak identification with migration time. The reliability of the identification with the relative mobility was 16 times better than that with migration time.更多还原