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提高AB5型贮氢电极合金低温电化学性能研究
Improvement of the Low Temperature Electrochemical Performance of AB5-type Hydrogen Storage Alloy
【摘要】 采用优化稀土成分并添加适量的硼改善AB5型贮氢合金的低温性能 .实验表明 ,含富Ce稀土及添加适量硼的AB5型合金 ,其低温电化学性能优良 ,能满足Ni/MH电池在低至 - 35℃小倍率电流密度放电的要求 .贮氢合金低温性能的改善与合金的微结构、热力学和动力学性能相一致
【Abstract】 Optimizing the rare earth composition and doping with boron have been used to improve the low temperature performance of AB 5 hydrogen storage alloy.The results show that Ce-rich alloy with a proper amount of boron is suitable for Ni/MH battery with the lower-limit temperature down to 238 K under smaller current density (120 mA/g). The improvement of low temperature performance of hydrogen storage alloy is well consistent with its microstructure,thermodynamic and kinetic properties.
【关键词】 贮氢合金;
电化学性能;
低温性能;
【Key words】 Hydrogen storage alloy; Electrochemical performances; Low temperature properties;
【Key words】 Hydrogen storage alloy; Electrochemical performances; Low temperature properties;
- 【文献出处】 电化学 ,Electrochemistry , 编辑部邮箱 ,2002年04期
- 【分类号】TM911
- 【被引频次】9
- 【下载频次】100