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制取低温度系数Nd-Fe-B磁体的混合合金法工艺

Binary Alloy Blending Method: a Way to Prepare Nd-Fe-B Magnets with Low Temperature Coefficient

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【作者】 成问好李卫李传健郭朝晖赵文彤

【Author】 Cheng Wenhao 1, Li Wei 1, Li Chuanjian 1, Guo Zhaohui 1, Zhao Wentong 2 (1 Central Iron & Steel Research Institute, Beijing 100081, China) (2 Tianjin Jinbin Magnetoelectrical Industry Co. Ltd., Tianjin 300457, China)

【机构】 钢铁研究总院天津津滨磁电有限公司 北京100081北京100081天津300457

【摘要】 将组成分别为 Nd3.5Dy30 .0 Fe6 5.5Nb0 .4 B1 .1 和 Nd33.5Fe30 .5Co35.0 Nb0 .4 B1 .1 (质量百分数 )的铸态 Nd- Fe- B合金按比例进行混合 ,使合金中的 (Dy+Co)总量基本保持不变 ,让 Dy和 Co的相对含量发生变化 ,采用粉末冶金工艺生产Nd- Fe- B磁体。结果发现 :磁体的 Br随着含 Co合金比例的增加线性增大 ,i H c随着含 Co合金比例的增加线性减小 ,但磁体的磁通可逆温度系数却只在较小的范围内变化。这说明当 (Dy+Co)含量保持在一定范围内时 ,既可以通过增加 Dy含量降低磁体的温度系数也可以通过增加 Co含量降低磁体的温度系数。在此研究的基础上 ,通过调整初始合金的成分和工艺 ,制成了磁性能为 18MGOe/2 3k Oe~ 2 5 MGOe/15 k Oe、磁通可逆温度系数为 - 0 .0 18% /℃~ -0 .0 2 6 % /℃的高稳定性、低温度系数 Nd- Fe- B系列磁体

【Abstract】 Sintered anisotropic Nd Fe B magnets with low temperature coefficient were prepared by binary alloy blending method (BABM). As cast Nd 3 5 Dy 30 0 Fe 65 5 Nb 0 4 B 1 1 (mass fraction) and Nd 33 5 Fe 30 5 Co 35 0 Nb 0 4 B 1 1 (mass fraction) pre alloys were produced separately. The above two kinds of alloys were mixed in a proportion to keep the total content of Dy and Co nearly constant, but the Dy/Co ratio varied in the different proportion of two kinds of alloys. It was found, under such a condition, B r increased almost linearly, but i Hc decreased linearly, with increasing Co containing alloy, the variation of the reversible temperature coefficient of the magnetic flux of the magnets was not apparent. It means, when the total content of Dy and Co keeps constant, the temperature coefficient of the magnet can be decreased by increasing Dy content or increasing Co content. However, the ratio of Dy/Co should be balanced when considering the coercivity i Hc of the magnets. The magnets with low temperature coefficient were prepared, their magnetic property parameters are as follows: ( BH ) max =18MGOe/23kOe~25MGOe/15kOe, α =-0 018%/℃~0 026%/℃.

  • 【文献出处】 稀有金属材料与工程 ,Rare Metal Materials and Engineering , 编辑部邮箱 ,2002年01期
  • 【分类号】TM271
  • 【被引频次】7
  • 【下载频次】160
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