【摘要】 目前文献中能查到的只有一些电极电势的简单温度系数 ,很少有电极电势与温度的关系方程式。本文通过测量原电池电动势的方法 ,测量不同温度下的锌电极与铜电极的电极电势 ,用计算机线性回归处理 ,得出锌电极与铜电极的电极电势与摄氏温度的关系分别为 :φ Zn2 + / Zn=-8× 10 -6t2 +2× 10 -3 t-0 .76 39;φ Cu2 + / Cu=3× 10 -6t2 -3× 10 -3 t+0 .3413。有这些关系式可以减少电化学测量中因温度变化引起的误差更多还原

【Abstract】 There are only some simple temperature coefficients of electrode electromotive and a few relation equations off electrmotive on reference books.After numerous experiments,we can deduce the relationships of the electrmotive of zinc and copper electrode between temperature represents as follows: φ  Zn 2+/Zn=-8×10 -6t 2+2×10 -3t-0.7639;φ  Cu 2+/Cu=3×10 -6t 2-3×10 -3+0.3413. The results of these experiments provide a reference,and can reduce errors caused by the changes of temperature in electrical chemistry measuring.更多还原