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HQ-PPEK/PC共混物的相容性与流变性

Miscibility and Rheological Properties of HQ-PPEK/PC Blends

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【作者】 廖功雄蹇锡高郭晓园李建丰宋宏

【Author】 LIAO Gong Xiong, JIAN Xi Gao , GUO Xiao Yuan, LI Jian Feng, SONG Hong (Department of Polymer Science,Dalian University of Science and Technology,Dalian 116012)

【机构】 大连理工大学化工学院高分子材料系大连理工大学化工学院高分子材料系 大连116012大连116012大连116012

【Abstract】 The blends of HQ PPEK, prepared by polymerization of 4 (4 hydroxyphenyl) 1 phthalazone(DHPZ) and hydroquinone(HQ)(1∶1 molar ratio) with 4,4 diflourodiphenylketone and polycarbonate(PC) through coprecipitation in chloroform solution. The miscibility of the blends was characterized by ternary solution methods and DSC. The results indicated that the blends were immiscible or partially miscible. The rheological properties of the blends were studied by capillary rheometer. The results show that the melt blends are psedoplastic fluids, the die swelling ratios decrease and the non Newtonian index increases with increase in the weight content of PC in the blends and the blends viscosity curves negatively does not follow the single additivity rule.

【基金】 国家自然科学基金资助项目 ( 5 947390 1)
  • 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,2001年11期
  • 【分类号】O631
  • 【被引频次】7
  • 【下载频次】110
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