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HQ-PPEK/PC共混物的相容性与流变性
Miscibility and Rheological Properties of HQ-PPEK/PC Blends
【Abstract】 The blends of HQ PPEK, prepared by polymerization of 4 (4 hydroxyphenyl) 1 phthalazone(DHPZ) and hydroquinone(HQ)(1∶1 molar ratio) with 4,4 diflourodiphenylketone and polycarbonate(PC) through coprecipitation in chloroform solution. The miscibility of the blends was characterized by ternary solution methods and DSC. The results indicated that the blends were immiscible or partially miscible. The rheological properties of the blends were studied by capillary rheometer. The results show that the melt blends are psedoplastic fluids, the die swelling ratios decrease and the non Newtonian index increases with increase in the weight content of PC in the blends and the blends viscosity curves negatively does not follow the single additivity rule.
【Key words】 poly(aryl ether ketone); polycarbonate; polymer blends; miscibility; rheology;
- 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,2001年11期
- 【分类号】O631
- 【被引频次】7
- 【下载频次】110