节点文献
L-亮氨酸与醋酸铜固相配位反应的热化学研究
Study on Thermochemistry of Solid State Coordination Reaction of L-Leucine with Copper Acetate
【Abstract】 The reaction enthalpy of solid-solid coordination reaction of L-Leucine with copper acetate is determined by solution calorimetry in an isoperibel reaction calorimeter. The calorimetric solvent is the solution of hydrochloric acid(4 mol/L), a new thermochemical cycle is designed. The values of ΔfHθm=15.64 kJ/mol, ΔfHθm(trans-Cu(L-Leu)2,s)=-1194.7 kJ/mol are evalcated.
【关键词】 L-亮氨酸;
醋酸铜;
固相配位反应;
热化学;
【Key words】 L-leucine; copper acetate; solid-solid state reaction; thermochemistry;
【Key words】 L-leucine; copper acetate; solid-solid state reaction; thermochemistry;
【基金】 教育部青年骨干教师计划;湖北省教委科学研究计划项目!(99CO44)
- 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,2001年02期
- 【分类号】O642.3;O627
- 【下载频次】67