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CuO/Al2O3催化剂中毒与氧吸附

Poisoning and Oxygen Adsorption of CuO/Al2O3 Catalyst

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【作者】 冯如彬姚宏伟

【Author】 FENG Ru Bin *, YAO Hong Wei (Chemistry Teaching Group,Hebei Institute of Architectural Science and Technology,Handan 056038)

【机构】 河北建筑科技学院化学教研室!邯郸056038

【Abstract】 The effect of CuSO 4 on the property of catalyst CuO/Al 2O 3 has been investigated. The TPD MS results showed that the amount of oxygen adsorbed on the surface of CuSO 4 CuO/Al 2O 3 increased with CuSO 4 content in the catalyst and the oxygen desorbed only at temperature above 900 K . TPSR results showed three adsorption sites of NO on the surface of CuO/Al 2O 3, respectively at 398, 643 and 683 K. The active site at 683 K was for NO decomposition and it was poisoned seriously when there was CuSO 4 in the CuO/Al 2O 3. For CuSO 4 CuO/Al 2O 3 the amount of N 2O formed from NO decomposition reduced probably due to the increase of oxygen species in the catalyst.

【关键词】 CuO/Al2O3CuSO4催化剂中毒氧吸附
【Key words】 CuO/Al 2O 3CuSO 4poisoningoxygen adsorption
  • 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,2001年01期
  • 【分类号】O643
  • 【被引频次】6
  • 【下载频次】108
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