节点文献
Cu(Ⅰ)(CH3COCHCOOEt)[P(NEt2)3]2配合物的电化学合成及表征
Electrochemical Synthesis and Characterization of Copper(Ⅰ) Complexes with Ethylacetoacetate and Hexaethylophosphorus Triamide
【摘要】 用牺牲金属阳极的电化学方法合成了一种新的一价铜配合物 Cu( ) (CH3COCHCOOEt) [P(NEt2 ) 3]2 ,对配合物进行了元素分析、红外光谱、核磁共振测试及表征 ,并研究了反应的机理 .
【Abstract】 The complexes of Cu(Ⅰ) with ethylacetoacetate and hexaethylophosphorus triamide were prepared by an electrochemical method in nonaqueous solvents. The product was characterized by elemental analysis, IR, 1H and 13 C NMR measurements as Cu(Ⅰ)(CH 3COCHCOOEt)[P(NEt 2) 3] 2. The mechanism of the electrochemical reactions is studied here.
【关键词】 一价铜配合物;
电化学合成;
非水溶剂;
【Key words】 copper(Ⅰ) complexes; electrochemical synthesis; nonaqueous solvent;
【Key words】 copper(Ⅰ) complexes; electrochemical synthesis; nonaqueous solvent;
- 【文献出处】 徐州师范大学学报(自然科学版) ,Journal of Xuzhou Normal University(Natural Science Edition) , 编辑部邮箱 ,2001年03期
- 【分类号】O641.4
- 【下载频次】79