节点文献
稀土配合物Na3Eu(DPA)3掺杂的PMMA树脂的制备及其发光性能
Preparation and Fluorescence of Sodium Tris (Pyridine Dicarboxylato) Europate Doped Polymethyl Methacrylate Resin
【摘要】 稀土配合物Na3Eu(DPA) 3具有良好的发光特性和热稳定性。采用加热方法将Na3Eu(DPA) 3掺入PMMA树脂中 ,制成发光塑料树脂 ,并测定了其发光性能。结果表明 ,Na3Eu(DPA) 3掺入PMMA树脂后 ,仍保持该稀土配合物原有的发光特性 ,制成的Na3Eu(DPA) 3 PMMA树脂复合材料具有良好的发光性能 ,其发光强度与Na3Eu(DPA) 3掺入的含量有关 ,但没有线性关系
【Abstract】 Based on the intense fluorescence and the highly thermal stability of sodium tris (pyridine dicarboxylato) europate (Na 3Eu(DPA) 3), its composite material with polymethyl methacrylate (PMMA) resin, PMMA: Na 3Eu(DPA) 3, was prepared at 250 ℃. The fluorescence for PMMA: Na 3Eu(DPA) 3 was determined. The results show that the composite material keeps the fluorescence characteristics of the Eu 3+ chelate after PMMA resin is incorporated with the complex Na 3Eu(DPA) 3, and strong orange red emission is observed. The fluorescence intensity for the composite material increases with the increase of the weight ratio of Na 3Eu(DPA) 3 to PMMA resin, non/inearly.
【Key words】 rare earths; rare earth complex; Na 3Eu(DPA) 3; polymethyl methacrylate resin; composite material; fluorescence;
- 【文献出处】 中国稀土学报 ,Journal of The Chinese Rare Earth Society , 编辑部邮箱 ,2001年03期
- 【分类号】O634
- 【被引频次】42
- 【下载频次】313