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多层碳纳米球的研究

Investigation on the Structure and Electric Properties of Bucky Onions

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【作者】 刘虹雯侯士敏刘赛锦陶成钢施祖进顾镇南彭练矛吴锦雷薛增泉

【Author】 Liu Hong- Wen Hou Shi- Min Liu Sai- Jin Tao Cheng- Gang Shi Zu- Jin1 Gu Zhen- Nan1 Peng Lian- Mao Wu Jin- Lei Xue Zeng- Quan (Department of Electronics, Peking University, Beijing 100871; 1College of Chemistry and Molecular Engineering, Peking Universit

【机构】 北京大学电子学系!北京 100871北京大学化学与分子工程学院!北京100871北京?

【摘要】 用弧光放电法制备了碳的巴基葱 .用原子力显微镜( AFM)、扫描隧道显微镜( STM)和透射电镜( TEM)研究了在高定向石墨 (HOPG)和金 (Au)基底上的巴基葱的行为和电学特性 .扫描隧道谱表明 ,巴基葱的电学特性具有与单壁碳纳米管相似的非线性特性 .较小尺寸的巴基葱呈半导体特性,尺寸增大倾向金属线性 .AFM/STM图像显示,在 HOPG和 Au基底上的巴基葱能够聚集成二聚体 .利用较小尺寸巴基葱的电学非线性特性, 有希望构造纳米电子学的单电子器件 .

【Abstract】 Bucky onions were fabricated by DC discharge method and their behaviors and electric properties on Highly Oriented Pyrolytic Graphite(HOPG) were studied using Atomic Force Microscope (AFM), Scanning Tunneling Microscope(STM) and Transmission Electron Microscope (TEM). Scanning Tunneling Spectroscopy showed that Bucky onions pocessed nonlinear electric properties similar to those of single- wall carbon nanotubes. Small- sized Bucky onions demonstrated the properties of semiconductors and as the size increased their metallicity became stronger. AFM and STM images revealed the tendency of Bucky onions to form dimers. Due to their nonlinear electric properties, Bucky onion is considered as a promising candidate for the future single electron devices.

【关键词】 巴基葱AFMSTM
【Key words】 Bucky onionsAFMSTM
【基金】 国家自然科学基金!( 69890221, 69701001)资助项目;教育部高等学校骨干教师资助计划资助课题;教育部科技研究重点项目!( 00005)
  • 【文献出处】 物理化学学报 ,Acta Physico-chimica Sinica , 编辑部邮箱 ,2001年05期
  • 【分类号】O613.71
  • 【被引频次】2
  • 【下载频次】325
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