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非平衡晶化控制水滑石晶粒尺寸

Control of Particle Size of Layered Double Hydroxides using Non-equilibrium Aging Conditions

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【作者】 赵芸; 矫庆泽; 李峰; Evans D.G; 段雪;

【Author】 ZHAO Yun JIAO Qing-Ze LI Feng Evans D.G.** DUAN Xue * (Key Laboratory of Science and Technology of Controllable Chemical Reactions,Ministry of Education,Beijing University of Chemical Tech nology,Beijing100029)

【机构】 北京化工大学可控化学反应科学与技术基础教育部重点实验室; 北京化工大学可控化学反应科学与技术?;

【摘要】 本文采用非平衡晶化法通过在晶化后期补加原料合成了一系列不同晶粒尺寸的水滑石LDH样品研究表明非平衡晶化法可在一定范围内调控LDH的粒径所合成的LDH样品组成稳定晶体结构完整。

【Abstract】 Mg /Al-layered double hydroxides(LDH)with different particle size have been prepared using non-equilibrium aging conditions b y supplying a solution of Mg (NO3)2·6H2O and Al (NO3)3·9H2O and a solution containing NaOH and Na 2CO3 at a later aging stage.It was found th at the particle size of LDH could be controlled to some extent by changing the quantities of salt and base added in the second step.Furthermore it was foun d that LDH samples with a stable composition and increased crystallinity could be synthesized by this method.

【基金】 中国石油化工集团公司资助项目(No.X59012)
  • 【文献出处】 无机化学学报 ,Chinese Journal of Inorganic Chemistry , 编辑部邮箱 ,2001年06期
  • 【分类号】O614
  • 【被引频次】116
  • 【下载频次】364
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