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碳钢阳极电溶解过程的电化学振荡现象
The Electrochemical Oscillatory Phenomena of the Process of the Anodic Electrodissolution of Carbon Steel
【摘要】 金属和合金阳极电溶解过程中常常可以观察到电化学振荡现象 ,尤其是在活化与钝化的转变阶段 .碳钢 / H2 SO4 / Pt体系在活化 -钝化转变过程中狭窄的电位范围内可以产生多种类型的电流振荡 ,如阻尼振荡、周期振荡、准周期振荡和混沌等 ,对其振荡机理进行了初步分析和讨论 .
【Abstract】 The electrochemical oscillations often are observed in the process of anodic electrodissolution of metal and alloy, in particular, in the transitional period of between activation and passivation. The various current oscillations,such as damp oscillation, periodic oscillation, quasi-periodic oscillation and chaos,can arise in the narrow range of potential where occurs the process of activation-passivation in the system of Carbon Steel/H 2SO 4/Pt, and its oscillatory mechanism is preliminarily discussed.
【关键词】 碳钢;
阳极电溶解;
电化学振荡;
【Key words】 Carbon steel; anodic electrodissolution; electrochemical oscillation;
【Key words】 Carbon steel; anodic electrodissolution; electrochemical oscillation;
【基金】 国家科技部公益性项目资助
- 【文献出处】 武汉大学学报(理学版) ,Wuhan University Journal(Natural Science Edition) , 编辑部邮箱 ,2001年04期
- 【分类号】O646.54
- 【被引频次】6
- 【下载频次】167