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Ni/海泡石及Ni/Sm海泡石催化剂的研究(英文)
STUDY OF Ni/SEPIOLITE AND Ni-Sm/SEPIOLITE CATALYSTS
【摘要】 用浸渍法制备了一系列含镍的催化剂,以TPR、TPD、XRD及XPS等手段分别对Ni/海泡石及Ni/Sm海泡石催化剂进行了表征。结果表明,助剂钐的加入不仅使镍粒变小,而且也降低了镍原子结合能,除此以外,镍的分散亦有提高。TPR与TPD测试表明钐的加入亦能引起峰温的变化。
【Abstract】 Ni/sepiolite and Ni-Sm/sepiolite catalysts were prepared by impregnation and their properties were characterized by the means of TPR, TPD, XRD and XPS, respectively. The results show that the addition of Sm to the Ni/sepiolite can decrease not only the partical size of nickel but also nickel atomic binding energy. Besides, it also increases the dispersion of nickel on sepiolite support. The reduction and desorption peak temperature in TPR or TPD curves changed after adding Sm.
【关键词】 镍催化剂;
海泡石;
钐;
CO2 甲烷化;
【Key words】 Ni/sepiolite; Ni-Sm/sepiolite; characterization; CO2 methanation;
【Key words】 Ni/sepiolite; Ni-Sm/sepiolite; characterization; CO2 methanation;
【基金】 This project was supported by the National Natural Science Foundation of China(No 29863002)
- 【文献出处】 Journal of Natural Gas Chemistry ,天然气化学杂志(英文版) , 编辑部邮箱 ,2001年01期
- 【分类号】O643.3
- 【被引频次】4
- 【下载频次】74