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PDADN-RDX-CMDB推进剂催化燃烧特性研究

Catalysis combustion property and mechanism of PDADN-RDX-CMDB propellant

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【作者】 李疏芬王进赵凤起王瑛许煜李上文

【Author】 LI Shu-fen 1,WANG Jin 1,ZHAO Feng-qi 2,WANG Ying 2,XU Yu 2,LI Shang-wen 2 (1.Dept. of Chemical Physics,Univ of Science and Technology of China,Hefei 230026,China; 2.Xi’an Modern Chemistry Research Inst.,Xi’an 710065,China)

【机构】 中国科技大学化学物理系!安徽合肥230026西安近代化学研究所!陕西西安710065

【摘要】 采用热分析、微热电偶技术、燃速测试、熄火表面的扫描电镜观测等实验方法 ,研究了不同类型的复合催化剂对PDADN RDX CMDB推进剂燃烧特性的影响。结果发现 ,邻苯二甲酸铅 /雷索辛酸铜 /炭黑与雷索辛酸铅铜 /炭黑两类复合催化剂可较好地改善PDADN RDX CMDB推进剂的燃烧特性 ,明显降低其压强指数且同时提高燃速 ,基于实验现象的观测结果分析 ,提出了“气泡 凝聚相反应”理论 ,解释了该类推进剂在中低压区发生的“超速燃烧”现象。

【Abstract】 In order to study effects of several kinds of composite catalysts on the combustion behavior of PDADN-RDX-CMDB propellant,different means such as thermogravimetric loss,microthermo couple,burning-rate experiment and SEM of quenched sample surface were adopted.The results show that two kinds of composite catalysts,which are ΦPb-βCu-CB and βPbCu-CB,can obviously improve the combustion behavior of PDADN-RDX-CMDB propellant,combustion pressure exponent are decreased and burning-rate are increased.The “bubble-condensation reaction” theory are proposed to explain “super rate combustion” phenomenon of PDADN-RDX-CMDB with composite catalysts propellant.

  • 【文献出处】 推进技术 ,Journal of Propulsion Technology , 编辑部邮箱 ,2001年02期
  • 【分类号】V512.2
  • 【被引频次】8
  • 【下载频次】118
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