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N—丙烯酰吩噻嗪二氧化物敏化的甲基丙烯酸甲酯的光聚合
Photopolymerization of methyl methacrylate sensitized by N acrylyl phenothiazine sulf dioxide
【摘要】 研究了N -丙烯酰吩噻嗪二氧化物 (APTDO)敏化甲基丙烯酸甲酯 (MMA)的光聚合 ,得到了APTDO敏化MMA光聚合的速率方程和表观活化能 ,用紫外光谱证实了APTDO不仅引发聚合 ,还参与聚合进入聚合物链中 ,并探讨了其引发机理
【Abstract】 The photopolymerization of Methyl Methacrylate by N acrylyl phenothiazine sulfdioxide(APTDO).It was found that the photopolymerization rate equations and Ea.From the UV analysis for PMMA sensitized by APTDO,it was confirmed that APTDO not only sensitized the photopolymerization of MMA but also entered into the PMMA chains.
【关键词】 丙烯酰吩噻嗪二氧化物;
甲基丙烯酸甲酯;
光聚合;
【Key words】 N-acrylyl-phenothiazine fuly; methyl methacrylate; photopolymerization;
【Key words】 N-acrylyl-phenothiazine fuly; methyl methacrylate; photopolymerization;
【基金】 河南省自然科学基金资助项目 (9840 310 0 0 )
- 【文献出处】 商丘师范学院学报 ,Journal of Shangqiu Teachers College , 编辑部邮箱 ,2001年04期
- 【分类号】O632
- 【下载频次】43