【摘要】 采用含环戊二烯络铁（FeCp）基团邻二氯苯和含羟基、巯基的二元酚类化合物合成含FeCp基团的二苯并二（口恶）英。实验中,以N,N-二甲基甲酰胺（DMF）为溶剂,室温下,在K2CO3弱碱性介质中,产品收率高,副反应少,反应时间短。通过1H NMR和13C NMR对该类产品结构的研究表明:产品纯度高;酚类的选择不同,H、C化学位移有一定差异。更多还原

【Abstract】 Dibenzo[1,4]dioxin compounds with cyclopentadienyliron complex were synthesized by cyclopentadienyliron complex of o-dichlorobenzene with o-dihydroxybenzene,2,3-dihydroxypyridine, 4-methyl-l,2-dimercaptobenzene in the presence of K2CO3 in DMF at room temperature. 1H NMR and 13C NMR showed that the products were pure and there were different chemical shifts if different starting materials were used.更多还原