节点文献
对苯二甲酸根桥联的铜配合物的合成和性质研究
Syntheses, Properties of Binuclear Copper(Ⅱ) Compound Bridged by Phthalic Anion
【摘要】 合成了两个以对苯二甲酸根为桥的双核铜配合物 通过元素分析确定了配合物的组成 ,并用红外、电导和紫外光谱表征了配合物 ,测定和研究了一个配合物的磁学性质
【Abstract】 Two novel compounds have been synthesized and characterized by elemental analysis, IR and UV-vis spectra. The temperature dependent-magnetic susceptibilities have been studied in the range 2-300 K, and the exchange integral 2J is found to be -48.6 cm -1 . The result suggests the moderately strong antiferromagnetic exchange interaction between the copper ions.
【关键词】 对苯二甲酸根;
铜配合物;
螯合配体;
反铁磁偶合;
【Key words】 p-phthalic bridge; copper(Ⅱ) compound; chelate ligand; magnetic properties;
【Key words】 p-phthalic bridge; copper(Ⅱ) compound; chelate ligand; magnetic properties;
- 【文献出处】 平顶山师专学报 ,Journal of Pingdingshan Teachers’ College , 编辑部邮箱 ,2001年02期
- 【分类号】O641.4
- 【下载频次】130