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煤热解过程中NO_x前驱物气体脱除的探讨

Study on the removing of NO_x precursors during coal pyrolysis

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【作者】 尤先锋刘美蓉刘生玉任军谢克昌

【Author】 YOU Xian-feng, LIU Mei-rong, LIU Sheng-yu, REN Jun, XIE Ke-chang (State Key Lab of C1 Chemistry and Technology, Shanxi Key Lab of Science & Technology, Taiyuan University of Technology,Taiyuan 030024,China)

【机构】 一碳化学与化工国家重点实验室山西省煤科学与技术重点实验室太原理工大学山西省煤科学?

【摘要】 研究了不同热解条件下煤中氮的释放 ,三个不同煤阶的中国煤样在 5 0 0~ 90 0℃之间以固定床和滴落式的反应器进行热解 ;考察了煤种、终温、粒径对于NOx 前驱物 (NH3 和HCN)在热解过程中释放的影响 ;产生的含氮气体 (NH3 和HCN)被相应的酸和碱吸收后用离子色谱测量

【Abstract】 This report describes the nitrogen releasing in coal pyrolysis at different conditions.Three Chinese coals of different rank were pyrolysed at temperature between 500?℃ and 900?℃ in a fixed-bed/drop-tube reactor at atmospheric pressure. The effects of coal rank, final temperature,particle sizes on the formation of NO x intermediates (HCN,NH 3) were considered.The yields of nitrogen-containing gases products(mainly NH 3,HCN) were determined as a function of pyrolysis temperature by ion chromatography after they were absorbed in basic and acidic solution,respectively.

【关键词】 煤热解NOx前驱物
【Key words】 coalcoal pyrolysisNO x precursors
【基金】 国家 973项目 0 1子课题 (G19990 2 2 10 1)
  • 【文献出处】 宁夏大学学报(自然科学版) ,Journal of Ningxia University(Natural Science Edition) , 编辑部邮箱 ,2001年02期
  • 【分类号】TQ530.2
  • 【被引频次】19
  • 【下载频次】146
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