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C₆₀臭氧化生成C₆₀O_n（n=1～5）的研究

STUDIES ON THE PRODUCT C₆₀O_n （n=15） OF THE OZONIZE OF C₆₀

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【Author】 HAO Ce 1,TENG Qiwen 1, WU Shi 1, SHANG Zhenfeng 1, LI Wenlan 1, PAN Yinming 1, GAN Weitang 1, TANG Aoqing 1,2 (1 Department of Chemistry, Nankai University, Tianjin, 300071; 2 Theoretical Institute of Chemistry, Jilin University, Changchu

【机构】南开大学化学系!天津； 300071； 300071吉林大学理论化学研究所；长春； 130023；

【摘要】对C60 臭氧化反应的产物C60 On 进行UV vis光谱测定和理论分析 .指认C60 On 异构体高效液相色谱 (HPLC)峰归属的可能结构 ,对HPLC峰的保留时间 (tR)与极性的相关性进行探讨 ,初步设想了反应的局部网络机理 .更多还原

【Abstract】 The electronic spectra of various fullerene oxides C 60 O n(n=1~5) introduced by ozonization have been studied, and the equilibrium structures as well as the electronic spectra have been predicted using semiempirical INDO method in this paper. The HPLC peaks of C 60 O n have been identified, the correlation between the retention times and dipoles of these fullerene oxides has been studied, and the network reaction mechanism has been introduced.更多还原