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离子膜原电池法还原钛液中的三价铁

Reduction of ferric iron in titanium sulfate solution by ion-exchange membrane primary cell method

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【作者】 李青刚; 周康根; 张启修; 张贵清;

【Author】 LI Qinggang, ZHOU Kanggen, ZHANG Qixiu, ZHANG Guiqing (Department of Metallurgical Scienceand Engineering, Central South University of Technology, Changsha 410083, China)

【机构】 中南工业大学冶金科学与工程系!长沙410083;

【摘要】 提出了离子膜原电池法还原钛液中的Fe3+新方法 .原电池的正极由铅 (或铜 )电极和钛液组成 ,负极由铁电极和酸性FeSO4 溶液组成 ,离子交换膜作为正负两极间的隔膜 ,利用原电池的放电过程还原钛液中的Fe3+.并详细地考察了温度、溶液电解液流速、膜面积等因素对还原速度的影响 ,实验结果表明 ,膜电流密度最大可达 10 0A/m2 以上

【Abstract】 A new method, called as the ino-exchange membrane primary cell method, for reduction of Fe 3+ in the titanium sulfate solution has been advanced. The positive compartment of the primary cell consist of lead(copper) electrode and the titanium sulfate solution, and the negative compartment consist of iron electrode and acidic FeSO 4 solution. The anion ion-exchange membrane is used as the diaphragm between two compartments. Fe 3+ in the titanium sulfate solution is reduced by the electric discharge of the primary cell. The effects of temperature, stitrring strength of the solution and membrane area on the reduction rate have been investigated. The experimental result shows that the optimum current density can be higher than 100 A/m 2.

【基金】 国家“九五”计划重点攻关项目
  • 【文献出处】 膜科学与技术 ,Membrane Science and Technology , 编辑部邮箱 ,2001年03期
  • 【分类号】TQ03
  • 【被引频次】2
  • 【下载频次】166
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