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热爆合成TiAl3临界温度判据的DSC研究

THE STUDY OF CRITERION FOR CRITICAL TEMPERATURE OF THERMAL EXPLOSION SYNTHESIS USING DIFFERENTIAL SCANNING CALORIMETRY

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【作者】 汪涛鲁玉祥祝美丽张俊善季世军

【Author】 WANG Tao, LU Yuxiang, ZHU Meili, ZHANG Junshan Department of Materials Engineering, Dalian University of Technology, Dalian 116024 JI Shijun Institute of Metal and Technology, Dalian Maritime University, Dalian 116026 Correspondent: WANG Tao, Tel: (0411)4

【机构】 大连理工大学材料工程系!大连116024大连海事大学金属工艺研究所!大连116026

【摘要】 以Ti-75%Al热爆合成体系为对象,研究了一种基于热爆炸理论的热爆临界温度(θ'ign)DSC判据在材料热爆合成领域中应用的可能性.采用该判据得到 Ti-75%Al体系在不同加热速率下的θ'ign,并结合多元线性回归法预测该体系等温热爆临界温度为 728.9 ℃,与由等温 DSC观察获得的 740——740 ℃的结果非常接近,从而证明该判据适用于快速确定金属二元系热爆合成的临界点燃温度

【Abstract】 Application of a novel criterion based upon the theory of thermal explosion for the critical temeprature (θ'ign) in thermal explosion (TE) synthesis was verified with the Ti-75%Al binary system using differential scanning calorimetry (DSC). The θ'ing values at different heating rates are evaluated by this criterion. And the critical temperature for isothermal TE is predicted to be 728.9 ℃ by multiple linear regression method, which closes to the range of 740-745 ℃ obtained from the isothermal DSC mesurement. The novel criterion is proved to be feasible for fast evaluation of θ'ign of TE synthesis in binary metallic TE systems.

【关键词】 点燃临界温度热爆合成DSC
【Key words】 ignitioncritical temperaturethermal explosion synthesisDSC
  • 【文献出处】 金属学报 ,Acta Metallrugica Sinica , 编辑部邮箱 ,2001年04期
  • 【分类号】TB39
  • 【被引频次】10
  • 【下载频次】132
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