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三塘湖盆地煤成油地球化学特征
Geochemical Characteristics of Coal derived Oil in Santanghu Basin
【摘要】 依据生物标志物分布和组成特征 ,可把三塘湖盆地的原油和油显示分成中生界煤成油和上古生界湖相成因原油两大类。中生界煤成油以塘参 1井中侏罗统西山窑组的原油为代表 ,表现为正构烷烃系列具明显的奇碳优势 ,Pr/Ph值高 ( >4 .0 ) ,四环萜烷 /三环萜烷 >1 .0 ,三环萜烷系列中 C1 9和 C2 0 相对丰度高于 C2 1和 C2 3,有 C31 六环藿烷 ,无伽玛蜡烷 ,C2 9甾烷占绝对优势 ,该原油源于中生界煤系源岩。上古生界湖相成因原油包括塘参 3井、条 2井和条 3井油显示 ,其主要特征为正构烷烃系列没有明显的奇偶优势 ,Pr/Ph值低 ,三环萜烷 /四环萜烷 (仅检测到 C2 4一个化合物 ) >1 .0 ,且 C2 1 和 C2 3 三环萜烷的相对丰度高于 C1 9和 C2 0 ,无 C31 六环藿烷 ,有较高含量的伽玛蜡烷和β-胡萝卜烷 ,C2 7甾烷丰度较高 ,它们源于该盆地上古生界湖相烃源岩
【Abstract】 According to the distribution and assemblage of biomarkers, the crude oil and oil shows from Santanghu basin can be classified into two groups, such as Mesozoic coal derived oil and oil of upper paleozoic lake facies genesis The crude oil from Xishanyao formation of Jurassic system in well Tangcan 1 is a representative of Mesozoic coal derived oil It has the characteristics of odd carbon predominance in normal alkane series,Pr/Ph value is high(>4 0) In addition,the relative abundance of C 24 C 26 tetracyclic terpanes is higher than C 19 C 25 tricyclic terpanes(>1 0), C 19 and C 20 components are higher than C 21 and C 23 in tricyclic terpanes, C 31 hexcyclic hopane is identified but gammacerane is not, C 29 components are unusually abundant in C 27 C 29 steranes The crude oil is originated from a coal measure source rock Oil from upper Paleozoic lake facies genesis includes the oil shows from wells of Tangcan 3, Tiao 2 and Tiao 3 They don’t have the characteristics of odd carbon predominance in normal alkanes and have lower Pr/Ph value Besides,the tricyclic terpanes are more abundant than tetracyclic terpanes (only C 24 is detected) and the relative abundance of C 23 and C 21 components is higher than tricyclic terpanes, C 31 hexcyclic hopane is substituted with abundant gammacerane and β carotane The abundance of C 27 steranes are comparatively higher,which are originated from the upper Paleozoic lake facies source rocks
【Key words】 coal derived oil; geochemical characteristic; biomarker; Santanghu basin;
- 【文献出处】 江汉石油学院学报 ,Journal of Jianghan Petroleum Institute , 编辑部邮箱 ,2001年01期
- 【分类号】P618.13
- 【被引频次】12
- 【下载频次】448