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四取代酞菁金属配合物异构体~1HNMR的表征
The Characterization Method of the Isomers of Tetra-substituted Metal Phthalocyanines by ~1H NMR
【摘要】 概述了近年来用1 HNMR表征一些四取代酞菁金属配合物异构体的研究进展情况。四取代酞菁配合物存在 4种异构体和 8种磁不等价的异吲哚基。这些磁不等价的异吲哚基对苯环上以及取代基的质子的1 HNMR谱均有所影响 ,因此可以通过测定这些质子的1 HNMR谱来确定异构体。
【Abstract】 The recent progress was presented briefly on the characterization method of the isomers of tetra-substituted~ metal phthalocyanines by 1H NMR. The tetra-substituted metal phthalocyanines were constituted~ by four isomers and eight magnetically nonequivalent isoindole units, which exert an influence on the protons of both the aromatic ring and substituted groups. Therefore, the symmetry of isomers can be confirmed by analysis of the 1H NMR spectra of these protons.
【关键词】 ~1HNMR;
酞菁金属配合物;
异构体;
表征;
【Key words】 ~1H NMR; tetra-substituted metal phthalocyanines; isomer; characterization;
【Key words】 ~1H NMR; tetra-substituted metal phthalocyanines; isomer; characterization;
【基金】 国家自然科学基金! (2 987110 0 8) ;国家重点科技项目! (攻关 )计划 (96 -90 1-0 1-6 7)资助项目
- 【文献出处】 结构化学 ,Chinese Journal of Structunal Chemistry , 编辑部邮箱 ,2001年02期
- 【分类号】O641.4
- 【被引频次】17
- 【下载频次】165