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PAN胶束增溶光度法测定铝合金中铜

MICELLAR SOLUBLIZING SPECTROPHOTOMETRIC DETERMINATION OF MICRO COPPER IN ALUMINUM ALLOY

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【作者】 寇兴明印红玲

【Author】 KOU Xing ming,YIN Hong ling (Faculty of Chemistry,Sichuan University,Chengdu 610064,China)

【机构】 四川大学化学学院!四川成都610064

【Abstract】 A direct spectrophotometric method for the determination of micro copper in aluminum alloy using PAN as chromogenic reagent has been proposed. In the presence of CTMAB,a stable red complex between Cu(Ⅱ) and PAN is formed in the buffer solution of pH1.3~4.5.The apparent molar absorptivity is 2.09×10 4L·mol -1 ·cm -1 at 558nm.The RSD is 0.8%(n=4).Beer’s law is obeyed for 0~80μg/25ml of Cu(Ⅱ).The linear correlation coefficient is 0.9998.

  • 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2001年02期
  • 【分类号】O657.3
  • 【被引频次】12
  • 【下载频次】87
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