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PAN胶束增溶光度法测定铝合金中铜
MICELLAR SOLUBLIZING SPECTROPHOTOMETRIC DETERMINATION OF MICRO COPPER IN ALUMINUM ALLOY
【Abstract】 A direct spectrophotometric method for the determination of micro copper in aluminum alloy using PAN as chromogenic reagent has been proposed. In the presence of CTMAB,a stable red complex between Cu(Ⅱ) and PAN is formed in the buffer solution of pH1.3~4.5.The apparent molar absorptivity is 2.09×10 4L·mol -1 ·cm -1 at 558nm.The RSD is 0.8%(n=4).Beer’s law is obeyed for 0~80μg/25ml of Cu(Ⅱ).The linear correlation coefficient is 0.9998.
【关键词】 铜;
1-(2-吡啶偶氮)-2-萘酚(PAN);
溴化十六烷基三甲基胺;
分光光度法;
铝合金;
【Key words】 copper; 1 (2 pyridylazo) 2 naphthol; cetyltrmethylammonium bromide; spectrophotometry; aluminum alloy;
【Key words】 copper; 1 (2 pyridylazo) 2 naphthol; cetyltrmethylammonium bromide; spectrophotometry; aluminum alloy;
- 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2001年02期
- 【分类号】O657.3
- 【被引频次】12
- 【下载频次】87