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手性双噁唑啉铜配合物在不对称合成中的应用
The Application of Chiral Bis-oxazoline Copper Complexes to the Asymmetric Synthesis
【摘要】 综述了手性双唑啉配体的主要结构类型 ,并讨论了手性双唑啉铜配合物在不对称Diels Alder反应、Ene反应、Mukaiyamaadol反应、烯丙基氧化、环丙烷化、氮杂环丙烷化等反应中的应用。
【Abstract】 The kinds of chiral bis\|oxazoline ligands and catalysts were summarized and the activities of catalysts were compared.The application of chiral bis\|oxazoline copper complexes to the asymetric Diels\|alder reaction,ene reaction allylic oxidation,cyclopropanation of olefins and aziridination of olefins were also discussed.
【关键词】 C2-对称性;
双唑啉;
手性双唑啉酮配合物;
不对称合成;
【Key words】 C\-2\|symmetric; Bis\|oxazoline; Chiral bis\|oxazoline copper complexes; Asymmetric synthesis;
【Key words】 C\-2\|symmetric; Bis\|oxazoline; Chiral bis\|oxazoline copper complexes; Asymmetric synthesis;
- 【文献出处】 化学通报 ,Chemistry , 编辑部邮箱 ,2001年10期
- 【分类号】O621
- 【被引频次】2
- 【下载频次】243