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两种新型含硅植物生长调节剂的合成及其生物活性

Synthesis and biological activity of new plant growth regulators containing silicon

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【作者】 李新生王德友陈义朗欧阳萌刘娟娟易均云黄耀宗

【Author】 Li Xinsheng, Wang Deyou, Chen Yilang,Ouyang Meng,Liu Juanjuan,Yi Junyun, Huang Yaozong (Department of Chemistry,Nanchang University, Nanchang 330047)

【机构】 南昌大学化学系!南昌330047

【摘要】 合成了2种新型含硅植物生长调节剂。它们的结构经元素分析、IR和1HNMR表征。生物活性试验表明,药液质量浓度为2.5mg/L时,2种目标化合物对水稻根生长比对照化合物1-萘乙酸乙基二甲硅基甲酯分别提高了10%和13%。

【Abstract】 Two plant growth regulators containing silicon- ethyldimethylsilylmethyl-5-ethy -etate and ethyldimethylsilylmethyl-5-isopropyl-1-naph- thylacetate were synthesized from 1-naphthylacetic acid, ethylbromide (isopropylbromide), trimethylchlorosilane and magnesium by Friedel-crafts alkylation,chlorination, Grignard reaction, nuleophilic substitution and elimination of potassium chloride. Their structures were characterized by elementary analysis, IR and 1HNMR spectra. The results of biological activity tests showed that at concentration of 25mg/L two target compounds increased the growth rate of the rice root by 10% and 13% than the ethyldimethylsilylmethyl-1-naphthylacetate(Ⅶ) respectively.

【关键词】 植物生长调节剂生物活性
【Key words】 plant growth regulatorssiliconbiological activity
【基金】 江西省自然科学基金资助项目!(1774)
  • 【分类号】TQ45
  • 【被引频次】6
  • 【下载频次】88
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