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配合物Eu（p-ABA）₃·phen·1.5H₂O的拉曼光谱

Raman spectrum of Eu（p-ABA）₃·phen·1.5H₂O complex

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【Author】 L Shuangxi 1) , A Youmei 2) ,LIU Wei 2) ,WANG Xinmin 1) , XU Hong 1) 1)Department of Inorganic Chemistry, Henan Medical University, Zhengzhou, 450052 2)Department of Pharmacy, Henan Medical University, Zhengzhou 450052

【机构】河南医科大学无机化学教研室；河南医科大学药学系；河南医科大学无机化学教研室郑州450052；郑州450052；郑州450052；

【摘要】目的 :利用光谱技术进行稀土配合物中羧基和邻二氮菲配位方式的研究。方法 :合成了Eu(p ABA) 3·phen·1.5H2 O配合物 (p ABA =对氨基苯甲酸根 ;phen =邻二氮菲 ) ,测定了该配合物的红外和拉曼光谱 ,进行了光谱指认。结果 :配合物Eu(p ABA) 3·phen·1.5H2 O中羧基和邻二氮菲都与Eu3+ 离子形成了配位键。结论 :利用光谱技术进行配合物中配位体配位方式的研究是一项很好的方法。更多还原

【Abstract】 Aim: Using spectrum technique to study coordinate mode of the carboxyl and 1,10 phenanthroline with the Eu 3+ in the coordination compound. Methods:Compound Eu(p ABA) 3·phen·1.5H 2O (p ABA: p aminobenzoate; phen: 1,10 phenanthroline) was synthesized. FT IR spectrum and FT Raman spectrum of Eu(p ABA) 3·phen·1.5H 2O complex was recorded,and the data was analyzed. Results: The carboxyl and 1,10 phenanthroline was proved to connect with the Eu 3+ in the Eu(p ABA) 3·phen·1.5H 2O.Conclusion: It is a good method to study coordinate mode of the carboxyl and 1,10 phenanthroline with the Eu 3+ in the coordination compound by spectrum technique.更多还原