节点文献
从马来酸酐合成富马酸二甲酯
Synthesis of Dimethyl Fumarate from Maleic Anhydride
【摘要】 马来酸酐和甲醇在一水硫酸氢钠存在下发生酯化反应 ,所得产物马来酸二甲酯在光和溴存在下转化成富马酸二甲酯 .该法有操作方便、反应条件温和、产品纯度高等优点
【Abstract】 By using sodium bisulfate monohydrate as catalyst,esterification reaction takes place between maleic anhydride and methanol.Then the intermediate,dimethyl maleate is isomerized into dimethyl fumarate under light and in the presence of bromine.The method has advantages of simple operation,mild reaction conditions and higher product purity.
【关键词】 硫酸氢钠;
催化剂;
酯化;
异构化;
富马酸二甲酯;
马来酸酐;
甲醇;
【Key words】 sodium bisulfate; catalyst; esterification; isomerization; dimethyl fumarate; maleic anhydride; methanol;
【Key words】 sodium bisulfate; catalyst; esterification; isomerization; dimethyl fumarate; maleic anhydride; methanol;
- 【文献出处】 海南大学学报(自然科学版) ,Natural Science Journal of Hainan University , 编辑部邮箱 ,2001年02期
- 【分类号】O623
- 【被引频次】9
- 【下载频次】294