【摘要】 采用Ｘ－射线四圆衍射方法，测定了三唑锡的晶体结构。结构分析表明，该配合物属于三斜晶系，空间群Ｐ－１，晶胞参数： ａ＝１３．９３６（３）■， ｂ＝１４．０３６（３）■，ｃ＝１７．６５１（４）■，α＝７９．８８（３）°，β＝７７．３２（３）°，γ＝８７．３６（３）°，ｚ＝３。三唑锡具有一维线形聚合物结构，锡原子的配位数是五，为三角双锥结构，１，２，４－三氮唑以１，４－氮原子参与配位，形成桥连结构。更多还原

【Abstract】 The crystal structure of azocyclotin was determined by X-ray single crystal diffraction ana- lysis. The crystallographic data are as follows: triclinic, space group P - 1, a=13.936(3)A, b = 14.036(3)A, c=17.651(4) A, α= 79.88(3)°, β = 77.32(3)°, γ= 87.36(3)°, z= 3. Azocyclotin molecule is a polymer with one-dimensional line shape. The complex number of tin atom is five, and with triangle-dicone struc- ture. Triazole-bridge is formed by complexing with 1, 4-N atom of 1, 2, 4-triazole.更多还原