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阴离子交换预浓集-中子活化法测定近岸海水样品中的超痕量铱

Ultra-trace analysis of iridium in coastal seawater sample by neutron activation analysis after anion exchange preconcentration

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【作者】 戴雄新王进春毛雪瑛柴之芳欧阳宏

【Author】 DAI Xiongxin WANG Jinchun MAO Xueying CHAI Zhifang OUYANG Hong (Institute of High Energy Physics and Laboratory of Nuclear Analysis Techniques, the Chinese Academy of Sciences, Beijing 100080)

【机构】 中国科学院高能物理研究所核分析技术开放研究实验室中国科学院高能物理研究所核分析技术开放研究实验室 北京100080

【摘要】 利用放射性192 Ir示踪技术及近紫外 -可见吸收光谱分析 ,研究了阴离子交换树脂对海水中铱的吸附行为 ,建立了天然海水样品中铱的阴离子交换预浓集流程 ,回收率达 90 %。在超净条件下 ,采用此流程结合中子活化分析测得黄海近岸海水样品中的铱浓度为 2 .6× 10 - 14 g/mL。

【Abstract】 The adsorption behaviors of iridium on an anion resin were studied through 192 Ir radiotracer technique and near ultra-violet and visible spectrum analysis. An anion exchange preconcentration procedure for iridium in natural seawater sample was established, and the recovery reached 90%. Under ultra-clean condition, the Ir concentration in a coastal seawater sample derived from the China Yellow Sea was determined by neutron activation analysis after this preconcentration procedure to be 2.6×10 -14 g/mL.

  • 【分类号】O657.4
  • 【被引频次】2
  • 【下载频次】59
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