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阴离子交换预浓集-中子活化法测定近岸海水样品中的超痕量铱
Ultra-trace analysis of iridium in coastal seawater sample by neutron activation analysis after anion exchange preconcentration
【摘要】 利用放射性192 Ir示踪技术及近紫外 -可见吸收光谱分析 ,研究了阴离子交换树脂对海水中铱的吸附行为 ,建立了天然海水样品中铱的阴离子交换预浓集流程 ,回收率达 90 %。在超净条件下 ,采用此流程结合中子活化分析测得黄海近岸海水样品中的铱浓度为 2 .6× 10 - 14 g/mL。
【Abstract】 The adsorption behaviors of iridium on an anion resin were studied through 192 Ir radiotracer technique and near ultra-violet and visible spectrum analysis. An anion exchange preconcentration procedure for iridium in natural seawater sample was established, and the recovery reached 90%. Under ultra-clean condition, the Ir concentration in a coastal seawater sample derived from the China Yellow Sea was determined by neutron activation analysis after this preconcentration procedure to be 2.6×10 -14 g/mL.
【关键词】 近岸海水;
铱;
阴离子交换;
中子活化分析;
【Key words】 Coastal seawater; Iridium; Anion exchange; Neutron activation analysis;
【Key words】 Coastal seawater; Iridium; Anion exchange; Neutron activation analysis;
- 【文献出处】 核技术 ,Nuclear Techniques , 编辑部邮箱 ,2001年10期
- 【分类号】O657.4
- 【被引频次】2
- 【下载频次】59