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丙烯环氧化中TS-1寿命

TS-1 LIFE IN EPOXIDATION OF PROPYLENE

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【作者】 陈晓晖何菲陈宪米镇涛许锡恩

【Author】 CHEN Xiaohui 1,HE Fei 2,CHEN Xian 3,MI Zhentao 1 and XU Xi’en 1( 1 School of Chemical Engineering, Tianjin University, Tianjin 300072, China; 2 State Key Laboratory of C1 Chemical Technology,Tianjin University,Tianjin?300072, China; 3

【机构】 天津大学化工学院!天津300072天津大学碳一国家重点实验室!天津300072福州大学化学化工学院!福建福州350002

【Abstract】 The TS-1 life in propylene epoxidation was studied in a continually slurry reactor under the condition of 40 ℃ and 0.4, 0.6 MPa. It is suggested that the single circle life of TS-1 was no less than 80 h, the conversation of hydrogen peroxide was over 90%, the selectivity of propylene oxide and 1-methoxy-2-propanol was above 92.1%. The TS-1 catalyst can be regenerated in methanol, the initial activity of regenerative catalyst can’t change after the slightly deactivation in first regeneration. Element C and Ti were analyzed by XPS. The new the shift of electronic binding energy showed that Ti had been lost and deactivated in reaction, much carton deposited on the surface of TS-1, which are the main reasons of TS-1 deactivation, and the continual propylene epoxidation can be realized integrated with the thermodynamic reactor and the proper process.

【关键词】 丙烯环氧化TS-1催化剂寿命XPS
【Key words】 propyleneepoxidationTS-1catalyst lifeXPS
【基金】 国家自然科学基金 (No .2 9792 0 70 );国家重点基础科学研究计划 (973) (No.G2 0 0 0 4 80 0 5)和SINOPEC联合资助项目&&
  • 【文献出处】 化工学报 ,Journal of Chemical Industry and Engineering(China) , 编辑部邮箱 ,2001年07期
  • 【分类号】TQ223.26
  • 【被引频次】4
  • 【下载频次】148
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