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碳酸化法制备α-Al(OH)3包覆CaCO3复合晶须

COATING α-Al(OH)3 ON ARAGONITE CALCIUM CARBONATE WHISKER THROUGH CARBONATION PROCESS

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【作者】 王德生刘庆峰刘斌陈寿田

【Author】 WANG Desheng,LIU Qingfeng,LIU Bin and CHEN Shoutian (Electrical Engineering Department, Xi’an Jiaotong University,Xi’an 710049,Shanxi,China)

【机构】 西安交通大学电气学院!陕西西安710049

【Abstract】 A carbonation process was developed to coat Al(OH) 3 on aragonite whisker. Al(OH) 3 coating was obtained in a suspension,which contained 3Cao·Al 2O 3·6H 2O(C 3AH 6)-NaOH prepared by adding Ca(OH) 2 to NaAlO 2 aqueous solution.The CaCO 3 whiskers coated with fine particles of Al(OH) 3 were prepared by blowing CO 2 gas into the suspension.The formed Al(OH) 3 adhered to the CaCO 3 fibers as the substrate.In order to coat α -Al(OH) 3 on aragonite whisker , the pH value of the solution must be higher than 10.5.The formation of C 3AH 6 and complexation of calcium carbonate molecule with C 3A were the domain factors to get single aragonite phase whisker. Micro-analysis demonstrated that the existence of Al(OH) 3 crystal coating on the surface of aragonite-type calcium carbonate whisker.After the coated whiskers were treated strongly in an ultrasonic water bath.Al(OH) 3 still adhered to the CaCO 3 whiskers well.The reaction mechanism was also mentioned in this paper.

【关键词】 CaCO3Al(OH)3晶须碳酸化
【Key words】 calcium carbonatealuminum hydratewhiskercarbonation process
  • 【文献出处】 化工学报 ,Journal of Chemical Industry and Engineering(China) , 编辑部邮箱 ,2001年06期
  • 【分类号】O78
  • 【被引频次】4
  • 【下载频次】87
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