【摘要】 系统地阐述了不同类型的溶剂在各种反应中的溶剂效应。结合以上内容及一些学者和本作者在一些溶剂中的甲醇羰基化实验。可以知道对甲醇羰基化这一反应 ,在极性溶剂中 ,极性较大且为非质子型的溶剂能显著提高反应的速率 ;在非极性溶剂中 ,介电常数较小的溶剂能增加反应速率。更多还原

【Abstract】 Solvent effects in the reaction of the carbonylation of methanol are studied.It is known that the presence of a solvent has a significant effcet on the rate of reaction.Nonpolar solvent with little dielectric constant has good effcet to the rate of the reaction,while larger polar solvent without H + also can increase the rate of the reaction.更多还原